Table 1 Selected list of catalysts for methanol dehydrogenation
From: Advances in CO2 circulation hydrogen carriers and catalytic processes
Catalyst | Solvent | Additive | Temp. (℃) | Time (h) | TON | TOF (h−1) | Refs. |
|---|---|---|---|---|---|---|---|
Ru-7 | H2O | 8Â M KOH | 72 | 552 | 350,000 | 200 | (Nielsen et al., 2013) |
Ru-8 | Toluene | KOH(a) | 100 | 720 | 29,000 | 40 | (Hu et al., 2014) |
Ru-9 | Dioxane/H2O | 8 M KOH | 82 | 4.5 | – | 55 | (van de Watering et al., 2016) |
Ru-10/Ru-11 | H2O | Triglyme | 93.5 | 192 | 4200 | 21 | (Monney et al., 2014) |
Ru-12 | H2O/THF | – | 90 | 10 | 2500(b) | 24,000(c) | (Rodriguez-Lugo et al., 2013) |
Ir-3 | H2O | NaOH(d) | 100 | 150 | 10,510 | 70 | (Fujita et al., 2015) |
Ir-4 | H2O | 0.5Â M KOH 8Â M KOH | 94 | 16 60 | 1400 1900 | 326(e) 31 | (Prichatz et al., 2017) |
Fe-2 | H2O | 8Â M KOH | 91 | 46 | 9834 | 644 | (Alberico et al., 2013) |
Mn-1 | H2O | 8 M KOH Triglyme | 92 | > 720 | > 20,000 | – | (Anderez-Fernandez et al., 2017) |